This study investigates the freezing behaviour of an Enceladus-type Na-Cl-CO3 solution using combined synchrotron X-ray computed microtomography and diffraction. The first observation of fluid inclusions in cryogenic natron (Na2CO3 . 10 H2O) is reported, establishing natron as a mineral of high astrobiological importance and arguing that future missions should prioritize sampling surface natron deposits for their potential to trap and preserve signatures of life.